90322-06-8

Upstream product

• 73430-27-0 1-dimethylamino-2-nitroethene 
• 126-81-8 dimedone 

Downstream Products

• 84636-81-7 2-(5,5-Dimethyl-3-oxo-cyclohex-1-enyloxy)-N-p-tolyl-acetamide 
• 84636-82-8 9,9-Dimethyl-4-p-tolyl-1-oxa-4-aza-spiro[4.5]decane-3,7-dione 
• 1011710-31-8 C₂₁H₂₃O₆^(1-)*K⁽¹⁺⁾ 
• 1011710-37-4 C₂₂H₂₅O₇^(1-)*K⁽¹⁺⁾ 
• 1011710-42-1 C₂₃H₂₈NO₆^(1-)*K⁽¹⁺⁾ 
• 1338465-11-4 potassium 4,4-dimethyl-1-(2-nitro-1-phenylethyl)-2,6-dioxocyclohexan-1-ide 
• 1338465-14-7 potassium 1-(1-(4-cyanophenyl)-2-nitroethyl)-4,4-dimethyl-2,6-dioxocyclohexan-1-ide 
• 1338465-08-9 potassium 1-(1-(4-methoxyphenyl)-2-nitroethyl)-4,4-dimethyl-2,6-dioxocyclohexan-1-ide 
• 1338465-16-9 potassium 4,4-dimethyl-1-(2-nitro-1-(4-nitrophenyl)ethyl)-2,6-dioxocyclohexan-1-ide 
• 1338465-13-6 potassium 1-(1-(4-bromophenyl)-2-nitroethyl)-4,4-dimethyl-2,6-dioxocyclohexan-1-ide 
• 1338465-10-3 potassium 4,4-dimethyl-1-(2-nitro-1-p-tolylethyl)-2,6-dioxocyclohexan-1-ide 

Relevant academic research and scientific papers

Phase-Transfer-Catalyzed Azo Coupling Reactions in Two-Phase Systems

The azo coupling reaction of p-methoxybenzenediazonium tetrafluoroborate with N,N-dimethylaniline has been investigated in a water-1,2-dichloroethane system.It has been found that, among the several additives examined, the phenolate ion, generated from picric acid or 2,4-dinitro-1-naphthol, acted as an effective phase-transfer catalyst.Further, the reaction of p-diethylaminobenzenediazonium tetrafluoroborate with dimedone, and active methylene compound, has also been investigated in the same two-phase system; a remarkable acceleration in the rate was observed in the presence of tetraalkyl onium salts, and even in their absence.

Electrophilicities of trans-β-nitrostyrenes

The kinetics of the reactions of the trans-β-nitrostyrenes 1a-f with the acceptor-substituted carbanions 2a-h have been determined in dimethyl sulfoxide solution at 20 °C. The resulting second-order rate constants were employed to determine the electrophile-specific reactivity parameters E of the trans-β-nitrostyrenes according to the correlation equation log k 2(20 °C) = sN(N + E). The E parameters range from -12 to -15 on our empirical electrophilicity scale (www.cup.lmu.de/oc/mayr/DBintro. html). The second-order rate constants for the reactions of trans-β- nitrostyrenes with some enamines were measured and found to agree with those calculated from the electrophilicity parameters E determined in this work and the previously published N and sN parameters for enamines.