90330-67-9Relevant academic research and scientific papers
CROSS DIENE-TRANSMISSIVE DIELS-ALDER CYCLOADDITION REACTION OF BIS(SILYLOXY) CROSS-CONJUGATED TRIENES.
Tsuge,Kanemasa,Sakoh,Wada
, p. 3234 - 3241 (2007/10/02)
Cross type of diene-transmissive Diels-Alder cycloaddition has been demonstrated by using two bis-silyloxy cross-conjugated trienes. The first cycloaddition stage of cross reaction, which has to be highly selective in the formation of mono-cycloadducts, h
CROSS TYPE OF DIENE-TRANSMISSIVE DIELS-ALDER REACTION
Tsuge, Otohiko,Kanemasa, Shuji,Sakoh, Hirohiko,Wada, Eiji
, p. 277 - 278 (2007/10/02)
The first example of cross type of diene-transmissive Diels-Alder reaction is presented by the reactions of an activated cross-conjugated triene, 3-(methoxymethylene)-2,4-bis(trimethylsilyloxy)-1,4-pentadiene, with cyclic olefins as the first dienophiles and then with acetylenes as the second.
