90340-63-9Relevant academic research and scientific papers
The Photochemistry of Alkyl 2-(Naphthalenyl)ethenylbenzoates:Photodehydrocyclization and Photodimerization Products and Their Structural Elucidation by 1H and 13C N.M.R.
Jones, Alan J.,Teitei, Tsutomu
, p. 561 - 576 (2007/10/02)
Irradiation of alkyl 2-benzoates in benzene gave the photodehydrocyclization product, the chrysenecarboxylates (3) as well as two of the photodimerization products, the cyclobutanes (6) and (7).Similarly, irradiation of alkyl 2
The Effects of Stereochemistry of the Bridging Atoms in o-Substituted Arylbenzoic Acids on Root Antigravitropism
Teitei, Tsutomu
, p. 1461 - 1466 (2007/10/02)
Compounds in which an aryl or heteroaryl ring is linked to the ortho position of a benzoic acid moiety by a bridging group of up to four atoms are shown to inhibit the gravitropic response of cress seedling roots between 1E-5 and 1E-8 M.No significant difference in inhibitory activity is observed between compounds containing up to four saturated or two partially unsaturated bridging atoms, although analogues containing three or four partially unsaturated bridging atoms are one to two orders of magnitude more active.Compounds in which the aryl nuclei are fused together are shown to be inactive at the highest concentration tested.The results have been interpreted in terms of the aryl groups in the molecule interacting with a hypothetical receptor site, with the bridging atoms acting as a more or less flexible coupling to facilitate such interaction.
The Synthesis and Anti-geotropic Activity of o-Arylethenylbenzoic Acids
Teitei, Tsutomu
, p. 1669 - 1674 (2007/10/02)
Fourteen new and three known o-arylethenylbenzoic acids (10-18), required for testing as potential plant growth regulators, have been synthesized by the Wittig reaction.The cis- and trans-isomers were separated by fractional crystallization and identified by NMR spectroscopy.The preliminary assay results on cress seedlings are reported and show that both geometric isomers appear to have nearly identical anti-geotropic activity in this test system.
