90347-65-2

Usage

Chemical compound

Benzenemethanol, 4-iodo-, acetate

Also known as

4-iodophenyl methanol acetate

Appearance

White to off-white crystalline solid

Molecular weight

290.07 g/mol

Uses

Intermediate in the synthesis of pharmaceuticals, agrochemicals, and other organic compounds; production of fine chemicals and specialty materials

Safety

Flammable, handle with care following proper safety precautions and guidelines

Upstream product

• 16004-15-2 1-bromomethyl-4-iodobenzene 
• 127-08-2 potassium acetate 
• 624-31-7 4-tolyl iodide 
• 108-24-7 acetic anhydride 
• 108-88-3 toluene 

Downstream Products

• 875556-32-4 (4-[(trimethylsilyl)methyl]phenyl)methyl acetate 
• 847362-28-1 [(C₅H₅)Fe(C₅H₄(CH₂)3OCH₂C₆H₄CCC₆H₄CH₂OC(O)CH₃)] 
• 872471-09-5 acetic acid 4-acetoxymethyl-2-phenylethynyl-benzyl-ester 

Relevant academic research and scientific papers

METHOD FOR PRODUCING IODIDE ESTER COMPOUND

PROBLEM TO BE SOLVED: To provide a method for producing an iodide ester compound that makes it possible to obtain a target iodide ester compound in high yield with high regioselectivity for iodine introduction. SOLUTION: A method for producing an iodide ester compound includes an iodide forming step in which: in the presence of a porous material, an ester compound represented by the following formula (2), iodine (I2), and an iodine-based oxide are reacted with each other, an iodide ester compound represented by the following formula (3) is formed. SELECTED DRAWING: None COPYRIGHT: (C)2020,JPO&INPIT

The electrosynthesis of diaryliodonium salts

A simple, one-step procedure for the synthesis of diaryliodonium salts is described. It is shown that the electrochemical oxidation of an aryl iodide at a carbon felt anode in acetic acid/25% acetic anhydride/5% sulfuric acid in the presence of an arene leads to a diaryliodonium salt in good yield. The method allows the preparation of unsymmetrical, as well as symmetrical diaryliodonium salts. (C) 2000 Elsevier Science Ltd.