90357-84-9

Upstream product

• 90357-71-4 (E)-2-Methyl-1-phenylsulfanyl-pent-1-en-3-one 
• 90357-80-5 (4-Methoxy-bicyclo[4.2.0]octa-1⁽⁶⁾,2,4-trien-7-yl)-(2-methoxy-ethoxymethoxy)-acetaldehyde 
• 1199-31-1 1-cyano-5-methoxybenzocyclobutane 

Downstream Products

• 90357-85-0 (E)-(4R,5R,6S)-6-(4-Methoxy-bicyclo[4.2.0]octa-1⁽⁶⁾,2,4-trien-7-yl)-6-(2-methoxy-ethoxymethoxy)-2,4-dimethyl-1-phenylsulfanyl-5-trimethylsilanyloxy-hex-1-en-3-one 
• 90357-86-1 (2S,3S,4R,4aS,10S,10aR)-6-Methoxy-4-(2-methoxy-ethoxymethoxy)-2,10a-dimethyl-10-phenylsulfanyl-3-trimethylsilanyloxy-3,4,4a,9,10,10a-hexahydro-2H-phenanthren-1-one 

Relevant academic research and scientific papers

STEREOSELECTIVE ADOL REACTION OF A LITHIUM Α-VINYL ENOLATE TO Α-ALKOXY ALDEHYDES

Stereoselective synthesis of the 4,5-syn, 5,6-anti adducts (14 and 16) on the aldol condensation of the Z(O)-lithium enolate, derived from the E-enone (2), to α-alkoxy adehydes (12 and 13) was proved via the successive intramolecular Diels-Alder reaction.