Cas 90357-85-0,(E)-(4R,5R,6S)-6-(4-Methoxy-bicyclo[4.2.0]octa-1<sup>(6)</sup>,2,4-trien-7-yl)-6-(2-methoxy-ethoxymethoxy)-2,4-dimethyl-1-phenylsulfanyl-5-trimethylsilanyloxy-hex-1-en-3-one

90357-85-0

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Basic information

Product Name: (E)-(4R,5R,6S)-6-(4-Methoxy-bicyclo[4.2.0]octa-1⁽⁶⁾,2,4-trien-7-yl)-6-(2-methoxy-ethoxymethoxy)-2,4-dimethyl-1-phenylsulfanyl-5-trimethylsilanyloxy-hex-1-en-3-one
Synonyms:
CAS NO:90357-85-0
Molecular Formula:
Molecular Weight: 558.811
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (E)-(4R,5R,6S)-6-(4-Methoxy-bicyclo[4.2.0]octa-1⁽⁶⁾,2,4-trien-7-yl)-6-(2-methoxy-ethoxymethoxy)-2,4-dimethyl-1-phenylsulfanyl-5-trimethylsilanyloxy-hex-1-en-3-one(CAS DataBase Reference)
NIST Chemistry Reference: (E)-(4R,5R,6S)-6-(4-Methoxy-bicyclo[4.2.0]octa-1⁽⁶⁾,2,4-trien-7-yl)-6-(2-methoxy-ethoxymethoxy)-2,4-dimethyl-1-phenylsulfanyl-5-trimethylsilanyloxy-hex-1-en-3-one(90357-85-0)
EPA Substance Registry System: (E)-(4R,5R,6S)-6-(4-Methoxy-bicyclo[4.2.0]octa-1⁽⁶⁾,2,4-trien-7-yl)-6-(2-methoxy-ethoxymethoxy)-2,4-dimethyl-1-phenylsulfanyl-5-trimethylsilanyloxy-hex-1-en-3-one(90357-85-0)

Safety Data

Hazard Codes: N/A
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Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
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Hazardous Substances Data: 90357-85-0(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 90357-85-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,0,3,5 and 7 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 90357-85:
(7*9)+(6*0)+(5*3)+(4*5)+(3*7)+(2*8)+(1*5)=140
140 % 10 = 0
So 90357-85-0 is a valid CAS Registry Number.

90357-85-0Upstream product

90357-85-0Downstream Products

90357-86-1 (2S,3S,4R,4aS,10S,10aR)-6-Methoxy-4-(2-methoxy-ethoxymethoxy)-2,10a-dimethyl-10-phenylsulfanyl-3-trimethylsilanyloxy-3,4,4a,9,10,10a-hexahydro-2H-phenanthren-1-one

90357-85-0Relevant academic research and scientific papers

STEREOSELECTIVE ADOL REACTION OF A LITHIUM Α-VINYL ENOLATE TO Α-ALKOXY ALDEHYDES

Ihara, Masataka,Chihiro, Masatoshi,Fukumoto, Keiichiro,Kametani, Tetsuji

, p. 373 - 376 (2007/10/02)

Stereoselective synthesis of the 4,5-syn, 5,6-anti adducts (14 and 16) on the aldol condensation of the Z(O)-lithium enolate, derived from the E-enone (2), to α-alkoxy adehydes (12 and 13) was proved via the successive intramolecular Diels-Alder reaction.

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