90359-86-7Relevant articles and documents
Synthesis of Steroids: Part IX - A New Approach Towards Synthesis of Estrone, 6-Thiaestrone and Their D-Homo Analogues
Jinaraj, V. K.,Muljiani, Z.,Ravindranathan, T.,Tilak, B. D.
, p. 841 - 845 (2007/10/02)
A new approach for the synthesis of estrone, 6-thiaestrone and their D-homo-analogues is described.This involves preparation of homoallyl halides (XIIIa, b) and C-alkylation of 2-methylcyclohexane-1,3-dione (Va) followed by cyclodehydration to the steroid