90394-16-4

Upstream product

• 72345-23-4 (2S,4S)-pentane-2,4-diol 
• 39515-51-0 3-Phenoxybenzaldehyde 

Downstream Products

• 90394-18-6 (S)-((S)-1-Methyl-3-oxo-butoxy)-(3-phenoxy-phenyl)-acetonitrile 
• 69410-05-5 2-(4-Chloro-phenylamino)-3-methyl-butyric acid (S)-1-(3-phenoxy-phenyl)-ethyl ester 
• 69410-05-5 2-(4-Chloro-phenylamino)-3-methyl-butyric acid (R)-1-(3-phenoxy-phenyl)-ethyl ester 
• 72902-77-3 (R)-1-(3-Phenoxy-phenyl)-ethanol 
• 72902-79-5 (S)-1-m-phenoxyphenyl-1-ethanol 
• 71962-66-8 (R)-2-hydroxy-2-(3-phenoxyphenyl)acetonitrile 
• 39515-47-4 (S)-m-phenoxybenzaldehyde cyanohydrin 
• 94424-97-2 (2S,4S)-4-[(R)-1-(3-Phenoxy-phenyl)-ethoxy]-pentan-2-ol 
• 94340-15-5 (2S,4S)-4-[1-(3-Phenoxy-phenyl)-ethoxy]-pentan-2-ol 

Relevant academic research and scientific papers

ASYMMETRIC SYNTHESIS VIA CHIRAL ACETAL TEMPLATES. 7. FURTHER STUDIES ON THE CYANATION REACTION. THE USE OF ACETALS DERIVED FROM DIOLS WITH ONE CHIRAL CENTER

New examples of the cyanation reaction are described, including one that affords the cyanohydrin 8, an intermediate for synthesizing pyrethroid insecticides.Also the reaction with acetals derived from S-1,3-butanediol has been examined.

ASYMMETRIC SYNTHESIS via CHIRAL ACETAL TEMPLATES. 8. REACTIONS WITH ORGANOMETALLIC REAGENTS

The titanium tetrachloride catalyzed coupling of organometallic reagents with chiral acetals 1 is shown to provide a convenient route for the preparation of a variety of chiral alcohols 4 of high optical purity.