90408-11-0

Basic information

• Product Name: 2,1-Benzisoxazol-3(1H)-one, 1-(phenylmethyl)-
• CAS NO: 90408-11-0
• Molecular Formula: C14H11NO2
• Molecular Weight: 225.247
• Mol File: 90408-11-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,1-Benzisoxazol-3(1H)-one, 1-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,1-Benzisoxazol-3(1H)-one, 1-(phenylmethyl)-(90408-11-0)
• EPA Substance Registry System: 2,1-Benzisoxazol-3(1H)-one, 1-(phenylmethyl)-(90408-11-0)

Safety Data

• Hazardous Substances Data: 90408-11-0(Hazardous Substances Data)

Upstream product

• 31499-90-8 2,1-benzisoxazol-3(1H)-one 
• 100-39-0 benzyl bromide 
• 34897-85-3 o-azidobenzoyl chloride 
• 579-73-7 2-hydroxylaminobenzoic acid 

Relevant articles and documents

The Pyrolysis of 2-Azidobenzoates. A New Synthesis of Carbazoles and Other N-Heterocycles

The spray pyrolysis of aryl 2-azidobenzoates yields carbazoles, involving a rearrangement whereby the nitrogen of the product is attached to the aryl 1-carbon, a process involving a spiro 6-membered intermediate.When the aryl ortho-positions were both alkyl substituted the product was ab acridan instead.With an ortho-carboxylate, acridone formation competed with that of carbazole.When the CO-O group of the substrate was replaced by O-CO, CO-S, CO-NPh, or SO2-O the pyrolysis was ineffective.Benzyl 2-azidobenzoates, however, pyrolysed to yield 1-benzyl-2,1-benzisoxazolones by an unprecedented C-O insertion reaction of the intermediate nitrene.