90434-25-6

Basic information

• Product Name: 1-(3-chlorophenyl)-N-methylmethanimine
• Synonyms: 1-(3-chlorophenyl)-N-methylmethanimine
• CAS NO: 90434-25-6
• Molecular Weight: 153.611
• Mol File: 90434-25-6.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 1-(3-chlorophenyl)-N-methylmethanimine(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(3-chlorophenyl)-N-methylmethanimine(90434-25-6)
• EPA Substance Registry System: 1-(3-chlorophenyl)-N-methylmethanimine(90434-25-6)

Safety Data

• Hazardous Substances Data: 90434-25-6(Hazardous Substances Data)

Upstream product

• 39191-07-6 3-chloro-N-methylbenzylamine 
• 593-51-1 methylamine hydrochloride 
• 587-04-2 m-Chlorobenzaldehyde 
• 74-89-5 methylamine 

Downstream Products

• 1262325-08-5 4-(3-chlorobenzylidene)-1,2-dimethyl-1H-imidazol-5(4H)-one 
• 1144106-38-6 C₁₂H₁₂ClNO 
• 883858-16-0 N-methyl-N-[1-(3-chlorophenyl)-2-(4-chlorophenyl)ethyl]amine 
• 39191-07-6 3-chloro-N-methylbenzylamine 

Relevant articles and documents

Enantioselective Reductive Coupling of Imines Templated by Chiral Diboron

We herein report a general, practical, and highly efficient method for asymmetric synthesis of a wide range of chiral vicinal diamines via reductive coupling of imines templated by chiral diboron. The protocol features high enantioselectivity and stereospecificity, mild reaction conditions, simple operating procedures, use of readily available starting materials, and a broad substrate scope. The method signifies the generality of diboron-enabled [3,3]-sigmatropic rearrangement.

Method for synthesizing imine by catalytic oxidation of asymmetric secondary amine in presence of visible light

The invention belongs to the technical field of chemical engineering and pharmaceutical industry, and particularly relates to a method for synthesizing imine by catalytic oxidation of asymmetric secondary amine in the presence of visible light. With aza-metalloporphyrin containing sulfur as a visible light catalyst, 1,8-diazabicycloundecene-7-alkene as an auxiliary agent, and oxygen as an oxidant,asymmetric secondary amine is subjected to catalytic oxidation under irradiation of visible light of lambda being larger than or equal to 420nm, so as to obtain the oxidation product imine. A new andefficient imine production way is provided.

A latent reaction in a model GFP chromophore revealed upon confinement: Photohydroxylation of ortho -halo benzylidene-3-methylimidazolidiones via an electrocylization process

Excited state behavior of halogen substituted model GFP chromophores was investigated in an acetonitrile solution and in a confined environment provided by an octa acid capsule in water. Of the ortho, meta, and para halogen substituted GFP chromophores on