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"μ-chloro-di[μ-bis(diphenylphosphino)amine-P,P']-bis[carbonyl-rhodium(I)]-tetraphenylborate-methanol" is a complex organometallic compound that features a central μ-chloro bridge connecting two rhodium(I) centers. Each rhodium is coordinated to a carbonyl ligand and a bis(diphenylphosphino)amine ligand, which provides a bidentate binding mode through its phosphorus atoms. The tetraphenylborate anion acts as a counterion, and methanol is present as a solvent molecule. μ-chloro-di[μ-bis(diphenylphosphino)amine-P,P']-bis[carbonyl-rhodium(I)]-tetraphenylborate-methanol is significant in the field of homogeneous catalysis, particularly for reactions involving carbon-carbon bond formation, due to its ability to stabilize and activate substrates through the rhodium centers. The structure and electronic properties of this complex make it a valuable tool for studying and facilitating various chemical transformations.

90443-69-9

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90443-69-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 90443-69-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,0,4,4 and 3 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 90443-69:
(7*9)+(6*0)+(5*4)+(4*4)+(3*3)+(2*6)+(1*9)=129
129 % 10 = 9
So 90443-69-9 is a valid CAS Registry Number.

90443-69-9Upstream product

90443-69-9Downstream Products

90443-69-9Relevant academic research and scientific papers

CHEMIE POLYFUNKTIONELLER MOLEKUELE. LXXVII. DAS REAKTIONSVERHALTEN VON BIS(DIPHENYLPHOSPHINO)AMIN GEGENUEBER DI-μ-CHLORO-BIS

Ellermann, Jochen,Szucsanyi, Gyopar,Geibel, Kurt,Wilhelm, Eberhard

, p. 297 - 320 (1984)

This paper describes the direct synthesis of the A-frame complex Rh2(μ-CO)(μ-Cl)(μ-Ph2PNHPPh2)2Cl2*CH3OH*O(C2H5)2 (IV') from 2 and Ph2PNHPPh2 (I).The intermediates formed, Cl*0.5O(C2H5)2 (Va), Rh2(μ-CO)(μ-Cl)(μ

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