904689-15-2

Basic information

• Product Name: N,N-bis(2-bromobenzyl)-N-(2-methylpropyl)amine
• Synonyms: N,N-bis(2-bromobenzyl)-N-(2-methylpropyl)amine
• CAS NO: 904689-15-2
• Molecular Weight: 411.179
• Mol File: 904689-15-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-bis(2-bromobenzyl)-N-(2-methylpropyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-bis(2-bromobenzyl)-N-(2-methylpropyl)amine(904689-15-2)
• EPA Substance Registry System: N,N-bis(2-bromobenzyl)-N-(2-methylpropyl)amine(904689-15-2)

Safety Data

• Hazardous Substances Data: 904689-15-2(Hazardous Substances Data)

Upstream product

• 78-81-9 isobutylamine 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 

Relevant articles and documents

Hypervalent organoantimony compounds 12-ethynyl-tetrahydrodibenz[c,f][1,5]azastibocines: Highly efficient new transmetallating agent for organic halides

Extremely efficient and high-speed ethynylation of acyl chlorides, aryl iodides and bromides was demonstrated by palladium-catalyzed cross-coupling reaction of N-t-butyl-Sb-ethynyl-5,6,7,12-tetrahydrodibenz[c,f][1,5]azastibocine under mild conditions. Optimization and generalization of the hypervalent antimony-mediated coupling reaction are presented in detail. Single-crystal X-ray analysis of the N-methyl-1,5-azastibocine revealed that the remarkable reactivity enhancement of the azastibocine was derived from elongation of the antimony-ethynyl carbon bond originated from Sb-N intramolecular non-bonding interaction.