90484-64-3Relevant academic research and scientific papers
Synthesis of 1,1-Disubstituted Indenes and Dihydronaphthalenes through C-C/C-C Bond-Forming Pd-Catalyzed Autotandem Reactions
Barroso, Raquel,Paraja, Miguel,Cabal, María-Paz,Valdés, Carlos
supporting information, p. 4086 - 4089 (2017/08/14)
A novel synthesis of 1,1-disubstituted 1H-indenes is described involving the Pd-catalyzed cascade reaction between o-bromophenyl-β-bromostyrenes and N-tosylhydrazones in a process comprising the consecutive formation of two Csp3-C bonds on the same carbon atom: the cross-coupling of the N-tosylhydrazone with the alkenyl bromide and the intramolecular Heck reaction on the newly formed double bond. A similar approach has been applied to the preparation of 1,1-disubstituted naphthalenes.
Gold-catalyzed intermolecular oxidation of o-alkynylbiaryls: An easy and practical access to functionalized fluorenes
Pan, Fei,Liu, Shuang,Shu, Chao,Lin, Rong-Kun,Yu, Yong-Fei,Zhou, Jin-Mei,Ye, Long-Wu
supporting information, p. 10726 - 10729 (2014/10/15)
A novel gold-catalyzed intermolecular oxidation of o-alkynylbiaryls has been developed. A variety of functionalized fluorenes are readily accessed by utilizing this non-diazo approach, thus providing a viable alternative to synthetically useful fluorenes. This journal is the Partner Organisations 2014.
A sequential metal-catalyzed C-N bond formation in the synthesis of 2-amido-indoles
Yao, Pei-Yuan,Zhang, Yu,Hsung, Richard P.,Zhao, Kang
supporting information; experimental part, p. 4275 - 4278 (2009/05/30)
(Chemical Equation Presented) A sequential metal-catalyzed C-N bond formation employing ortho-haloaryl acetylenic bromides is described. The initial amidation is highly selective for C8P-N bond formation, leading to o-haloaryl-substiluted ynami
