824-54-4

Basic information

• Product Name: 2-Bromo-4-methylbenzaldehyde
• Synonyms: 2-BROMO-P-TOLUALDEHYDE;2-BROMO-4-METHYLBENZALDEHYDE;2-Bromo-4-methylbenzaldehyde ,98%;2-BROMO-4-2-Bromo-4-methylbenzaldehyde;2-Bromo-4-methylbenzaldehyde,2-bromo-p-tolualdehyde;2-Bromo-p-tolualdehyde, 3-Bromo-4-formyltoluene;2-Bromo-4-methylbenzaldehyde technical grade
• CAS NO: 824-54-4
• Molecular Formula: C₈H₇BrO
• Molecular Weight: 199.04
• EINECS: 1312995-182-4
• Product Categories: Aldehydes;Building Blocks;C8;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
• Mol File: 824-54-4.mol
• Article Data: 11

Chemical Properties

• Melting Point: 30-35 °C(lit.)
• Boiling Point: 254.1 °C at 760 mmHg
• Flash Point: >230 °F
• Appearance: /
• Density: 1.49 g/cm³
• Vapor Pressure: 0.0176mmHg at 25°C
• Refractive Index: 1.597
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive: Air Sensitive
• CAS DataBase Reference: 2-Bromo-4-methylbenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Bromo-4-methylbenzaldehyde(824-54-4)
• EPA Substance Registry System: 2-Bromo-4-methylbenzaldehyde(824-54-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 824-54-4(Hazardous Substances Data)

Usage

Chemical Properties

White to yellow solid

Uses

Different sources of media describe the Uses of 824-54-4 differently. You can refer to the following data:
1. 2-Bromo-4-methylbenzaldehyde is a useful intermediate for organic synthesis.
2. Reactant involved in:Carbonylative Stille couplings followed by isomerization and intramolecular Heck reactionsKnoevenagel condensationCyclization of N-(α-methyl-p-methoxybenzyl)-imino-estersImination and oxidative heterocyclization / carbonylationIntramolecular aminationIntermolecular and intramolecular hydroacylation of alkenes by aromatic aldehydes
3. Reactant involved in:? ;Carbonylative Stille couplings followed by isomerization and intramolecular Heck reactions1? ;Knoevenagel condensation2? ;Cyclization of N-(α-methyl-p-methoxybenzyl)-imino-esters3? ;Imination and oxidative heterocyclization / carbonylation4? ;Intramolecular amination5? ;Intermolecular and intramolecular hydroacylation of alkenes by aromatic aldehydes6

InChI:InChI=1/C8H7BrO/c1-6-2-3-7(5-10)8(9)4-6/h2-5H,1H3

Upstream product

• 7697-27-0 2-bromo-4-methylbenzoic acid 
• 42872-73-1 4-methyl-2-bromobenzonitrile 
• 104-85-8 para-methylbenzonitrile 
• 824-53-3 2,6-dibromo-4-methylbenzyl alcohol 
• 7745-91-7 3-bromo-4-methylaniline 
• 75-17-2 formaldoxime 
• 938461-09-7 2-bromo-N-methoxy-N,4-dimethylbenzamide 
• 591-17-3 meta-bromotoluene 
• 100-97-0 hexamethylenetetramine 
• 583-68-6 2-bromo-p-toluidine 
• 50-00-0 formaldehyd 

Downstream Products

• 1015731-87-9 5-methyl ortho-formylphenylacetylene 
• 1251839-61-8 (6-methyl-1H-inden-2-yl)(phenyl)methanone 
• 1246965-71-8 2-bromo-1-(2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-4-methylbenzene 
• 838820-88-5 1-phenyl-6-methyl-1H-indazole 
• 1523213-23-1 2-bromo-4-methyl((triethylsilyloxy)methyl)benzene 
• 18377-65-6 methyl 6-methyl-1H-indole-2-carboxylate 
• 16732-81-3 6-methyl-1H-indole-2-carboxylic acid ethyl ester 
• 1608462-00-5 benzyl 6-methyl-1H-indole-2-carboxylate 
• 1350467-54-7 (E)-ethyl 3-(2-Formyl-5-methylphenyl)acrylate 

Relevant articles and documents

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