90493-86-0

Basic information

• Product Name: Acetamide, N-hydroxy-N-(2-iodophenyl)-
• CAS NO: 90493-86-0
• Molecular Formula: C8H8INO2
• Molecular Weight: 277.062
• Mol File: 90493-86-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Acetamide, N-hydroxy-N-(2-iodophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-hydroxy-N-(2-iodophenyl)-(90493-86-0)
• EPA Substance Registry System: Acetamide, N-hydroxy-N-(2-iodophenyl)-(90493-86-0)

Safety Data

• Hazardous Substances Data: 90493-86-0(Hazardous Substances Data)

Upstream product

• 609-73-4 o-nitroiodobenzene 
• 41319-82-8 2-iodophenyl hydroxylamine 
• 75-36-5 acetyl chloride 

Relevant articles and documents

Redox-Neutral Selenium-Catalysed Isomerisation of para-Hydroxamic Acids into para-Aminophenols

A selenium-catalysed para-hydroxylation of N-aryl-hydroxamic acids is reported. Mechanistically, the reaction comprises an N?O bond cleavage and consecutive selenium-induced [2,3]-rearrangement to deliver para-hydroxyaniline derivatives. The mechanism is studied through both 18O-crossover experiments as well as quantum chemical calculations. This redox-neutral transformation provides an unconventional synthetic approach to para-aminophenols.