90504-29-3Relevant academic research and scientific papers
NUCLEOPHILIC RECYCLIZATION OF β-CARBOLINES - NEW VARIANT OF THE SYNTHESIS OF THE CARBAZOLE RING
Stupnikova, T. V.,Kirilash, A. R.,Zemskii, B. P.,Klyuev, N. A.,Dulenko, V. I.,Sagitullin, R. S.
, p. 159 - 165 (1984)
The reaction of salts of 1,3-dimethyl-9H-pyridoindole with hydroxide ions was examined within the framework of the Pariser-Parr-Pople (PPP) method.It is shown that the reaction may stop at the step involving the formation of an anhydro base (R = H) or lead to recyclization products (R = CH3, C2H5), viz., carbazole derivatives.The calculated data are in good agreement with the experimental data.
