90504-36-2Relevant articles and documents
Stereoselectivity in amidyl radical cyclisations. Acyl mode cyclisations
Clark, Andrew J.,Peacock, Joanne L.
, p. 6029 - 6032 (1998)
Amidyl radicals generated from tributylstannane mediated homolysis of O- benzoyl hydroxamic acid derivatives undergo 5-exo cyclisation to give mixtures of cis and trans pyrrolidinones. While the steric nature of the nitrogen substituents investigated had
Amide groups switch selectivity: C-H trifluoromethylation of α,β-unsaturated amides and subsequent asymmetric transformation
Li, Lei,Guo, Jing-Yao,Liu, Xing-Guo,Chen, Su,Wang, Yong,Tan, Bin,Liu, Xin-Yuan
supporting information, p. 6032 - 6035 (2015/01/16)
The first direct C-H β-trifluoromethylation of unsubstituted or α-alkyl-substituted α,β-unsaturated carbonyl compounds under metal-free conditions was realized with excellent regio- and stereoselectivity as well as a very broad substrate scope. Both olefi
Notiz zur Aminolyse von Dibenzoyl-peroxid mit primaeren Aminen
Psiorz, Manfred,Zinner, Gerwalt
, p. 217 (2007/10/02)
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