90542-87-3Relevant academic research and scientific papers
Metalated Nitriles: Internal 1,3-asymmetric induction
Fleming, Fraser F.,Liu, Wang
supporting information; experimental part, p. 699 - 708 (2009/07/17)
Stereoselective alkylations of acyclic, metalated nitrites are intimately controlled by a remote stereocenter. Probing the optimal steric demand through alkylations with a series of substituted pentanenitriles reveal the fundamental requirements for 1,3-a
One-Pot, selective hydroformylation, condensation, and hydrogenation processes by a sol-gel entrapped rhodium complex, an immobilized base, and an ionic liquid
Hamza, Khalil,Schumann, Herbert,Blum, Jochanan
experimental part, p. 1502 - 1505 (2009/07/11)
We report on a one-pot, multistep process in which styrene derivatives are selectively hydroformylated to give branched aldehydes, which in turn, are condensed with reactive methylene compounds (malononitrile, ethyl cyanoacetate), and then hydrogenaled. T
Dendritic nanoreactor encapsulating Rh complex catalyst for hydroformylation
Mizugaki, Tomoo,Miyauchi, Yasuaki,Murata, Makoto,Ebitani, Kohki,Kaneda, Kiyotomi
, p. 286 - 287 (2007/10/03)
A Rh phosphine complex was encapsulated within the surface alkylated poly(propylene imine) dendrimers through ionic interactions. The resulting dendrimer complexes functioned as nanoreactors for hydroformylation of olefins. The congested surface of dendrimers with long alkyl chains favored hydroformylation of higher olefins. One-pot three reactions composed of hydroformylation, the Knoevenagel reaction, and hydrogenation proceeded within the dendritic nanoreactor. Copyright
