90544-07-3

Upstream product

• 90544-06-2 1-Mesitoyloxy-2,6-dimethyl-octadien-(2trans,6trans)-ol-⁽⁸⁾ 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 37905-03-6 8-hydroxygeranyl acetate 
• 37905-02-5 (2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 35334-60-2 (E)-6-acetoxy-4-methyl-4-hexenal 
• 135897-92-6 ethyl (2E,6E)-8-hydroxy-2,6-dimethylocta-2,6-dienoate 
• 52527-84-1 ethyl (2E,6E)-8-acetoxy-2,6-dimethyl-2,6-octadienoate 
• 938-18-1 mesitylene-2-carboxylic acid chloride 
• 90544-05-1 2,4,6-Trimethyl-benzoic acid (2E,6E)-8-acetoxy-2,6-dimethyl-octa-2,6-dienyl ester 

Downstream Products

• 90544-08-4 (4E,8E)-10-mesitoyloxy-2,2,5,9-tetramethyldeca-4,8-dienal 
• 90544-09-5 2,4,6-Trimethyl-benzoic acid (2E,6E)-11,11-dichloro-2,6,9,9-tetramethyl-undeca-2,6,10-trienyl ester 
• 6753-98-6 α-caryophyllene 

Relevant academic research and scientific papers

NEW STEREO- AND REGIOSPECIFIC SYNTHESIS OF HUMULENE BY MEANS OF THE PALLADIUM CATALYZED CYCLIZATION OF HALOALKENYLBORANES

We describe a new stereo- and regiospecific synthesis of humulene, the major sesquiterpene of hops, by means of the palladium-catalyzed cyclization of haloalkenylboranes derived from geranyl halides via 4 principal steps.