905449-74-3Relevant academic research and scientific papers
Palladium-catalyzed hydrogenation: Detection of palladium hydrides. A joint study using para-hydrogen-enhanced NMR spectroscopy and density functional theory
Lopez-Serrano, Joaquin,Duckett, Simon B.,Lledos, Agusti
, p. 9596 - 9597 (2007/10/03)
Pd(PEt3)2(OTf)2, acting as an in situ source of Pd(PEt3)2, reacts with an alkyne and hydrogen via phosphine loss to form the detectable hydride-containing species Pd(PEt3)2(H)(CHPhCH2Ph), cis- and trans-Pd(PEt3)2(H)(CPh=CHPh), and Pd2(PEt3)3(H)(CHPhCH2Ph)2+, which map onto the reaction scheme predicted by density functional theory. Copyright
