905588-26-3Relevant academic research and scientific papers
Generation of rhodium enolates via retro-aldol reaction and its application to regioselective aldol reaction
Murakami, Kei,Ohmiya, Hirohisa,Yorimitsu, Hideki,Oshima, Koichiro
, p. 2388 - 2390 (2008/09/18)
Retro-aldol reactions of β-hydroxy ketones take place under rhodium catalysis, leading to regioselective formation of the corresponding rhodium enolates. The enolates react with aldehydes in situ to afford the corresponding aldol adducts in high yields.
β-Hydroxy Ketones from the Iodine-catalysed Reaction of α-Bromo Ketone with Aldehydes Mediated by Trialkylstibine
Huang, Yao-Zeng,Chen, Chen,Shen, Yanchang
, p. 2855 - 2860 (2007/10/02)
β-Hydroxy ketones can be synthesized in excellent yield by the iodine-catalysed reaction of α-bromo ketones with various aldehydes mediated by trialkylstibine.
