90601-11-9

Basic information

• Product Name: Phosphonium, [2-(dimethylamino)ethenyl]triphenyl-, chloride
• CAS NO: 90601-11-9
• Molecular Formula: C22H23NP.Cl
• Molecular Weight: 367.858
• Mol File: 90601-11-9.mol

Chemical Properties

• CAS DataBase Reference: Phosphonium, [2-(dimethylamino)ethenyl]triphenyl-, chloride(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonium, [2-(dimethylamino)ethenyl]triphenyl-, chloride(90601-11-9)
• EPA Substance Registry System: Phosphonium, [2-(dimethylamino)ethenyl]triphenyl-, chloride(90601-11-9)

Safety Data

• Hazardous Substances Data: 90601-11-9(Hazardous Substances Data)

Upstream product

• 598-56-1 N,N-dimethyl-ethanamine 
• 603-35-0 triphenylphosphine 
• 1071-38-1 N,N,N',N'-Tetramethylformamidinium chloride 
• 19493-09-5 Methylenetriphenylphosphorane 

Downstream Products

• 90601-12-0 <2-(Dimethylamino)-1-methylvinyl>triphenylphosphonium-chlorid 
• 5773-12-6 <2-(Dimethylamino)vinyl>diphenylphosphanoxid 
• 24720-64-7 2-(triphenylphosphoranylidene)propionaldehyde 
• 82248-14-4 <2-(Dimethylamino)vinyliden>triphenylphosphoran 
• 2136-75-6 (triphenylphosphoranylidene)acetaldehyde 

Relevant articles and documents

45. A Facile Conversion of Tertiary Amines into triphenylphosphonium Salts

Halogenation of Et3N, (i-Pr)2EtN, and N-ethylmorpholine or of enamines with dichlorotriphenylphosphorane gives in up to 75percent yield the corresponding triphenylphosphonium chlorides, which can be readily converted into the corres

Reactions with Phosphine Alkylenes, XLV. Reactions of Alkylidenetriphenylphosphoranes with Tetramethylformamidinium Chloride. Synthesis of triphenylphosphonium Chloride and (Formylalkylidene)triphenylphosphoranes

Phosphonium ylides 1 react with tetramethylformamidinium chloride (2) to form enamine phosphonium chlorides 8 and the formic orthoamide 7.The salts 8 show temperature depending 1H NMR spectra with respect to the protons of the dimethylamino group (hindered rotation around the C - N(CH3)2 bond).Treatment of 8 with acids and subsequently with bases gives rise to the formation of the formyl ylides 19. 8a is deprotonated with sodium amide to give the phosphaallene ylide 20, which reacts with water to yield the phosphane oxide 21, and with methyl iodide stereospecifically to form 8b.