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1071-38-1

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1071-38-1 Usage

Uses

(Dimethylaminomethylene)dimethylammonium chloride (N,N,N′,N′-tetramethylformamidinium chloride) may be used in the synthesis of the following:aminomethylene hydantoins thiohydantoins2,2′-o-phenyl-enebis(1,3-di-meth-ylguanidine)N,N-dimethylformamide di-tert-butyl acetal

General Description

(Dimethylaminomethylene)dimethylammonium chloride is an amidine derivative.

Check Digit Verification of cas no

The CAS Registry Mumber 1071-38-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,0,7 and 1 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1071-38:
(6*1)+(5*0)+(4*7)+(3*1)+(2*3)+(1*8)=51
51 % 10 = 1
So 1071-38-1 is a valid CAS Registry Number.
InChI:InChI=1/C5H13N2.ClH/c1-6(2)5-7(3)4;/h5H,1-4H3;1H/q+1;/p-1

1071-38-1 Well-known Company Product Price

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  • Aldrich

  • (391875)  (Dimethylaminomethylene)dimethylammoniumchloride  97%

  • 1071-38-1

  • 391875-5G

  • 562.77CNY

  • Detail

1071-38-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name (Dimethylaminomethylene)dimethylammonium chloride

1.2 Other means of identification

Product number -
Other names dimethylaminomethylidene(dimethyl)azanium,chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1071-38-1 SDS

1071-38-1Relevant articles and documents

-

de Vries,L.

, p. 926 - 933 (1978)

-

-

Toeniskoetter,R.H.,Killip,K.A.

, p. 690 - 694 (1964)

-

Nickel-Catalyzed Enantioselective Cross-Coupling of N-Hydroxyphthalimide Esters with Vinyl Bromides

Suzuki, Naoyuki,Hofstra, Julie L.,Poremba, Kelsey E.,Reisman, Sarah E.

supporting information, p. 2150 - 2153 (2017/04/27)

An enantioselective Ni-catalyzed cross-coupling of N-hydroxyphthalimide esters with vinyl bromides is reported. The reaction proceeds under mild conditions and uses tetrakis(N,N-dimethylamino)ethylene as a terminal organic reductant. Good functional group tolerance is demonstrated, with over 20 examples of reactions that proceed with >90% ee.

Orthoamides and iminium salts LXXIV [1]. Reactions of N,N,N',N'- Tetramethyl-chloroformamidiniumChloride with metals

Kantlehner, Willi,Aichholz, Reiner,Karl, Martin

, p. 305 - 319 (2012/07/13)

N,N,N',N'-Tetramethyl-formamidinium chloride (2a) reacts with elemental sodium in various solvents to give N,N,N',N',N'',N''-hexamethyl-guanidinium chloride (4a). The reaction of 2a with potassium affords N,N,N',N',N'',N'',N''', N'''-octamethyl-oxamidinium dichloride (3a). From the reaction of 2a with magnesium in different solvents in general result mixtures of the salts 4a, 3a and N,N,N',N'-tetramethyl-formamidinium chloride (10a). The composition of these mixtures depends on the solvent and the reaction temperature. Similar results are obtained, when a zinc'copper couple is used instead of magnesium. Very likely from 2a and magnesium or zinc, respectively, organometallic intermediates 11, 12 are formed which could be trapped by aromatic aldehydes and phenylisocyanate. The salt 2a can be reductively coupled by a low-valent titanium reagent to give the oxamidinium salt 3a.

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