906076-60-6

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 606129-11-7 (1R,2S)-5-Benzenesulfonyl-2-methyl-cyclohepta-3,5-dienol 
• 906076-66-2 ((1S,2S,3R,7S)-6-Benzenesulfonyl-2-methyl-8-oxa-bicyclo[5.1.0]oct-5-en-3-yloxy)-tert-butyl-dimethyl-silane 
• 75-16-1 methylmagnesium bromide 
• 917-54-4 methyllithium 

Downstream Products

• 906076-66-2 ((1S,2S,3R,7S)-6-Benzenesulfonyl-2-methyl-8-oxa-bicyclo[5.1.0]oct-5-en-3-yloxy)-tert-butyl-dimethyl-silane 
• 945931-73-7 C₂₀H₃₀O₄SSi 
• 906076-70-8 (1S,4R,6R,7S)-3-Benzenesulfonyl-6-(tert-butyl-dimethyl-silanyloxy)-4-(3,5-dimethyl-pyrazol-1-yl)-7-methyl-cyclohept-2-enol 
• 945931-76-0 C₂₁H₃₄O₄SSi 
• 945931-93-1 C₂₁H₃₂O₄SSi 
• 945931-94-2 C₂₁H₃₄O₄SSi 
• 945931-92-0 C₂₇H₃₈O₄S₂Si 
• 945931-86-2 C₂₅H₃₈N₂O₄SSi 
• 906076-72-0 (1S,2S,6R,7S)-3-Benzenesulfonyl-6-(tert-butyl-dimethyl-silanyloxy)-2,7-dimethyl-cyclohept-3-enol 
• 906076-87-7 (1S,2R,6R,7S)-3-Benzenesulfonyl-6-(tert-butyl-dimethyl-silanyloxy)-2,7-dimethyl-cyclohept-3-enol 

Relevant academic research and scientific papers

Second-generation synthesis of syn- and anti-cycloheptadienylsulfone polyketide stereodiads

(Chemical Equation Presented) Stereodiad sulfones 18a and 18b are key intermediates for polyketide synthesis. This note describes the synthesis of 18a and 18b from enantiopure epoxide 2. The two sequences have been optimized for large-scale synthesis to g

Asymmetric synthesis of all eight seven-carbon dipropionate stereotetrads

Enantiopure cycloheptadienyl sulfones 6 and 7 are diastereoselectively epoxidized to yield epoxyvinyl sulfones 8, 9, 14, and 16 in high yields and diastereomeric ratios. Syn and anti methylation of epoxides 8, 9, 14, and 16 enables access to all eight pos