90610-49-4

Basic information

• Product Name: 2-amino-3-hydroxy-4-methoxybenzoic acid methyl ester
• Synonyms: 2-amino-3-hydroxy-4-methoxybenzoic acid methyl ester
• CAS NO: 90610-49-4
• Molecular Weight: 197.191
• Mol File: 90610-49-4.mol

Chemical Properties

• CAS DataBase Reference: 2-amino-3-hydroxy-4-methoxybenzoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-amino-3-hydroxy-4-methoxybenzoic acid methyl ester(90610-49-4)
• EPA Substance Registry System: 2-amino-3-hydroxy-4-methoxybenzoic acid methyl ester(90610-49-4)

Safety Data

• Hazardous Substances Data: 90610-49-4(Hazardous Substances Data)

Upstream product

• 90564-40-2 methyl 3-hydroxy-4-methoxy-2-nitrobenzoate 
• 67-56-1 methanol 
• 1143525-64-7 limazepine D 

Downstream Products

• 1450821-37-0 (9aS,E)-8-ethylidene-3-methoxy-1-phenyl-7,8,9,9a-tetrahydro-1H-2-oxa-6a,10adiazabenzo[cd]cyclopenta[g]azulene-6,10-dione 
• 90222-57-4 2-amino-3-hydroxy-4-methoxybenzoic acid 

Relevant articles and documents

The exocyclic olefin geometry control via Ireland-Claisen rearrangement: Stereoselective total syntheses of Barmumycin and Limazepine e

Stereoselective total syntheses of Limazepine E and Barmumycin, potent, naturally occurring antitumor agents, are described. The total syntheses control the olefin geometry via a highly selective chelation-controlled Ireland-Claisen rearrangement of a seven-membered lactone-derived boron enolate for the synthesis of (E)-4-ethylidene proline, a crucial building block for a number of natural products.

Limazepines A-F, pyrrolo[1,4]benzodiazepine antibiotics from an Indonesian Micrococcus sp.

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