90635-35-1Relevant academic research and scientific papers
Dinuclear gold complexes of two simple but underutilized dicarbanionic ligand types
Coetzee, Karolien,Strasser, Christoph E.,Cronje, Stephanie,Raubenheimer, Helgard G.
, p. 1449 - 1457 (2010/09/16)
Both mono- and bisylide zwitterionic complexes of gold(I), [(C 6F5){PhCH(PPh3)}Au] (4), [(C6F 5)2(C6H4-p){CH(PPh 3)}2Au2] (5) and [(C
4,4'-OCTAFLUOROBIPHENYLGOLD(I) COMPLEXES
Uson, R.,Laguna, A.,Laguna, M.,Colera, I.,Jesus, E. De
, p. 121 - 130 (2007/10/02)
ClAu(tht) and LiRRLi (RR=4,4'-C6F4-C6F4; tht=tetrahydrothiophen) react to give (HRR)Au(tht) and (tht)AuRRAu(tht), which with neutral or anionic ligands, undergo two types of reactions: (a) replacement of the tht and formation of the complexes (HRR)AuL, LAuRRAuL (L=PPh3, SbPh3 or phen), - or -; (b) migration of the organic groups, leading to complexes of the types (L=SbPh3, L2=pdma), 2 or .
