906359-92-0Relevant academic research and scientific papers
PROCESS FOR PRODUCING 1,2-TRANS-GLYCOSIDE COMPOUND
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Page/Page column 14, (2010/11/28)
In preparing a glycoside compound from (a) a furanose compound or pyranose compound, and (b) an alcohol compound, a process for preparing a glycoside compound in which glycosidic bond locates selectively trans form relative to C-2 hydroxyl group, the proc
Dialkylphosphates as stereodirecting protecting groups in oligosaccharide synthesis
Yamada, Takeshi,Takemura, Kazunobu,Yoshida, Jun-Ichi,Yamago, Shigeru
, p. 7575 - 7578 (2008/02/01)
(Chemical Equation Presented) Double duty: A phosphoric ester at the C2 position in glycosyl donors directs the glycosylation to occur selectively at the anomeric carbon atom with complete 1,2-trans selectivity. Since the phosphoric ester can be removed to give the hydroxy function, this group serves as a stereodirecting protecting group in oligosaccharide synthesis.
