90649-81-3Relevant academic research and scientific papers
PhICl2 and wet DMF: An efficient system for regioselective chloroformyloxylation/a-chlorination of alkenes/a,β-unsaturated compounds
Liu, Le,Zhang-Negrerie, Daisy,Du, Yunfei,Zhao, Kang
supporting information, p. 436 - 439 (2014/04/03)
PhICl2 in wet DMF was found to form an efficient system for realizing difunctionalization of various alkenes and olefinic derivatives possessing a wide range of functional groups. This novel methodology provides convenient access to either regioselective chloroformyloxylated products or a-chlorinated olefinic products, depending on the type of structure of the original unsaturated starting material. The mechanism of the reaction is proposed and discussed.
