90664-13-4

Basic information

• Product Name: (3R,4R,5E)-(+)-4-Methoxy-3-methyl-6-phenyl-5-hexennitril
• Synonyms: (3R,4R,5E)-(+)-4-Methoxy-3-methyl-6-phenyl-5-hexennitril
• CAS NO: 90664-13-4
• Molecular Weight: 215.295
• Mol File: 90664-13-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3R,4R,5E)-(+)-4-Methoxy-3-methyl-6-phenyl-5-hexennitril(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,5E)-(+)-4-Methoxy-3-methyl-6-phenyl-5-hexennitril(90664-13-4)
• EPA Substance Registry System: (3R,4R,5E)-(+)-4-Methoxy-3-methyl-6-phenyl-5-hexennitril(90664-13-4)

Safety Data

• Hazardous Substances Data: 90664-13-4(Hazardous Substances Data)

Upstream product

• 90664-10-1 (1E,3S,4R)-(-)-3-Methoxy-4-methyl-5--1-phenyl-1-penten 
• 90664-09-8 (1E,3S,4R)-(-)-4-Methyl-5--1-phenyl-1-penten-3-ol 
• 70633-78-2 (3R,4E)-(-)-3-Hydroxy-5-phenyl-4-pentensaeure-methylester 
• 90664-11-2 (2R,3S,4E)-(+)-3-Methoxy-2-methyl-5-phenyl-4-penten-1-ol 
• 90695-51-5 (2R,3S,4E)-(-)-2-Methyl-5-phenyl-4-penten-1,3-diol 
• 90695-53-7 (2S,3S,4E)-(-)-3-Hydroxy-2-methyl-5-phenyl-4-pentensaeure-methylester 
• 143-33-9 sodium cyanide 
• 90664-12-3 (2R,3S,4E)-(-)-(3-Methoxy-2-methyl-5-phenyl-4-pentenyl)-p-toluolsulfonat 

Downstream Products

• 90695-50-4 (2E,3R,4S,5E)-methyl 4-methoxy-2-(methoxymethylene)-3-methyl-6-phenylhex-5-enoate 
• 73341-71-6 (2Z,3R,4S,5E)-(+)-4-Methoxy-2-(methoxymethylen)-3-methyl-6-phenyl-5-hexensaeure-methylester 
• 90695-52-6 (3R,4R,5E)-(+)-4-Methoxy-3-methyl-6-phenyl-5-hexensaeure-methylester 

Relevant articles and documents

Syntheses of (+)-Oudemansin and (+)-Epioudemansin Starting from Enantiomerically Pure Precursors; Absolute Configuration of the Naturally Occuring (-)-Oudemansin

The syntheses of the four optically pure methyl (E)-3-hydroxy-2-methyl-5-phenyl-4-pentenoates (+)- and (-)-5 as well as (+)- and (-)-6 were achieved by consecutive methylation and protonation of enolates, starting from (+)- and (-)-4.The esters (+)-6 and