90676-81-6

Basic information

• Product Name: Cyclohexaneethanol, 1-hydroxy-b-methyl-
• CAS NO: 90676-81-6
• Molecular Formula: C9H18O2
• Molecular Weight: 158.241
• Mol File: 90676-81-6.mol

Chemical Properties

• CAS DataBase Reference: Cyclohexaneethanol, 1-hydroxy-b-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexaneethanol, 1-hydroxy-b-methyl-(90676-81-6)
• EPA Substance Registry System: Cyclohexaneethanol, 1-hydroxy-b-methyl-(90676-81-6)

Safety Data

• Hazardous Substances Data: 90676-81-6(Hazardous Substances Data)

Upstream product

• 31042-01-0 methyl (1-hydroxy-α-methylcyclohexane)acetate 
• 849066-87-1 Allyl-[2-(5-bromo-pentyl)-[1,3]dithian-2-yl]-dimethyl-silane 
• 108-94-1 cyclohexanone 
• 849066-95-1 6-bromo-1-(allyldimethylsilyl)-1-hexanone 

Downstream Products

• 123903-25-3 2-(1-hydroxycyclohexan-1-yl)propanal 

Relevant articles and documents

Group transfer from silicon to carbon via tandem radical cyclizations of acylsilanes

Tandem radical cyclizations of acylsilanes with alkene or alkyne functionalities attached to silicon afforded cyclic silyl ethers which were oxidatively hydrolyzed to give diols or ketone alcohols.

The study of intramolecular tandem radical cyclizations of acylsilanes with radicalphiles attached on silicon

Radical cyclizations of acylsilanes with radicalphilic pendant introduced on silicon proceeded in a tandem fashion to give spiro products containing a cyclic silyl ether skeleton. Because the alkoxysilyl group can be replaced with a hydroxy group through

The stereoselective synthesis of oxetanes; exploration of a new, Mitsunobu-style procedure for the cyclisation of 1,3-diols

A solution of 2-methyl-3-[1-(phenylsulfanyl)cyclohexyl]propane-1,3-diol 1 in toluene treated with triphenyl-phosphine, Ziram 2 and DEAD, gave 3-methyl-2-[1-(phenylsulfanyl)cyclohexyl]oxetane 3 in 85% yield. A mechanistic study has been undertaken, optimal conditions have been found and the range of substrates for which the reaction is useful has been explored. We include the results of an X-ray study which shows that compound 33 (the oxidation product of diol 1) is a sulfone rather than a sulfoxide as previously reported.