31042-01-0

Basic information

• Product Name: methyl 2-(1-hydroxycyclohexyl)propanoate
• CAS NO: 31042-01-0
• Molecular Formula: C₁₀H₁₈O₃
• Molecular Weight: 186.2481
• Mol File: 31042-01-0.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 256.1°C at 760 mmHg
• Flash Point: 99.1°C
• Density: 1.07g/cm³
• Vapor Pressure: 0.00236mmHg at 25°C
• Refractive Index: 1.48
• CAS DataBase Reference: methyl 2-(1-hydroxycyclohexyl)propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(1-hydroxycyclohexyl)propanoate(31042-01-0)
• EPA Substance Registry System: methyl 2-(1-hydroxycyclohexyl)propanoate(31042-01-0)

Safety Data

• Hazardous Substances Data: 31042-01-0(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 292638-85-8 acrylic acid methyl ester 
• 554-12-1 propanoic acid methyl ester 
• 17639-93-9 2-chloro-propionic acid methyl ester 
• 802294-64-0 propionic acid 
• 5634-52-6 1,1-dimethoxy-propene 
• 5445-17-0 Methyl 2-bromopropionate 

Downstream Products

• 66957-29-7 (C₄H₉)3SnOC₆H₁₀CH(CH₃)COOCH₃ 
• 40556-79-4 methyl 2-cyclohexylpropionate 
• 6051-13-4 2-cyclohexylpropanoic acid 
• 65426-80-4 2-Cyclohexyl-propancarbonsaeure-p-nitrophenylester 
• 116505-07-8 2-cyclohexylpropanoyl chloride 
• 90676-81-6 1-(2-hydroxy-1-methylethyl)cyclohexanol 
• 62184-70-7 methyl 2-(1-cyclohexenyl)propanoate 
• 16112-64-4 4-Methyl-5,5-pentamethylen-2-oxazolidon 

Relevant articles and documents

Reductive aldol-type reaction of α,β-unsaturated esters with aldehydes or ketones in the presence of Rh catalyst and Et2Zn

The reaction of RhCl(PPh3)3 with Et2Zn easily generated a rhodium-hydride complex (Rh-H) that added to α,β-unsaturated esters to form rhodium enolate complexes by formal 1,4-reduction. These rhodium enolates gave the corre

Iron-catalysed Reformatsky-type reactions

A Reformatsky-type reaction has been developed using iron catalysis in acetonitrile or DMF. Reduction of iron(II) bromide by manganese metal in acetonitrile provides a low-valent iron catalyst, which is the active species; under these conditions, α-chloro

The stereoselective synthesis of oxetanes; exploration of a new, Mitsunobu-style procedure for the cyclisation of 1,3-diols

A solution of 2-methyl-3-[1-(phenylsulfanyl)cyclohexyl]propane-1,3-diol 1 in toluene treated with triphenyl-phosphine, Ziram 2 and DEAD, gave 3-methyl-2-[1-(phenylsulfanyl)cyclohexyl]oxetane 3 in 85% yield. A mechanistic study has been undertaken, optimal conditions have been found and the range of substrates for which the reaction is useful has been explored. We include the results of an X-ray study which shows that compound 33 (the oxidation product of diol 1) is a sulfone rather than a sulfoxide as previously reported.