90687-73-3Relevant academic research and scientific papers
HALOGENATED ETHERS. XXI. EFFECT OF TEMPERATURE AND SUBSTITUENT ON THE KINETIC OF THE FORMATION OF 2-(2-R-ETHOXY)-4,6-DICHLORO-SYM-TRIAZINES
Marchukov, V. A.,Nikitin, O. A.,V'yunov, K. A.,Ginak, A. I.
, p. 2282 - 2286 (2007/10/02)
The effect of temperature on the kinetics of the formation of 2-(2-R-ethoxy)-4,6-dichloro-sym-triazines from 2,4,6-trichloro-sym-triazine and 2-R-ethanol in the presence of alkali was investigated.The low values of the activation energy and the large negative values of the entropy indicate the participation of a stable intermediate in the investigated complex many-stage reaction.The mechanism of the process and the characteristics of the manifestation of isokinetic relationships are discussed.
