90696-32-5

Basic information

• Product Name: 2-Azetidinone, 1-(4-methoxyphenyl)-3-(1-methylethyl)-4-[(trimethylsilyl)ethynyl]-, trans-
• CAS NO: 90696-32-5
• Molecular Formula: C18H25NO2Si
• Molecular Weight: 315.488
• Mol File: 90696-32-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Azetidinone, 1-(4-methoxyphenyl)-3-(1-methylethyl)-4-[(trimethylsilyl)ethynyl]-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Azetidinone, 1-(4-methoxyphenyl)-3-(1-methylethyl)-4-[(trimethylsilyl)ethynyl]-, trans-(90696-32-5)
• EPA Substance Registry System: 2-Azetidinone, 1-(4-methoxyphenyl)-3-(1-methylethyl)-4-[(trimethylsilyl)ethynyl]-, trans-(90696-32-5)

Safety Data

• Hazardous Substances Data: 90696-32-5(Hazardous Substances Data)

Upstream product

• 104-94-9 4-methoxy-aniline 
• 2975-46-4 3-(trimethylsilyl)prop-2-yn-1-al 
• 108-64-5 Ethyl isovalerate 
• 90696-41-6 4-methoxy-N-(3-trimethylsilylpropynylidene)aniline 

Relevant articles and documents

N-Trimethylsilyl Imines: Applications to the Synthesis of β-Lactams

Ester enolates and N-trimethylsilyl imines react to afford N-protio-β-lactams.The stereochemical course of the reaction depends on the ester enolate geometry.Therefore (E)-enolates give mainly cis β-lactams while (Z)-enolates give nearly equal mixtures of cis and trans β-lactams.The use of ethyl β-hydroxybutyrate as the ester component allows the preparation of β-lactams of potential use in carbapenem synthesis.The differences in the behavior of N-trimethylsilyl and N-aryl imines in ester-imine condensations are also discussed.