90738-00-4

Basic information

• Product Name: [((C₂H₅)3P)2Pd(S₂CNH(CH₂C₆H₅))]⁽¹⁺⁾*Cl^(1-)=[((C₂H₅)3P)2Pd(S₂CNH(CH₂C₆H₅))]Cl
• CAS NO: 90738-00-4
• Molecular Weight: 560.481
• Mol File: 90738-00-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [((C₂H₅)3P)2Pd(S₂CNH(CH₂C₆H₅))]⁽¹⁺⁾*Cl^(1-)=[((C₂H₅)3P)2Pd(S₂CNH(CH₂C₆H₅))]Cl(CAS DataBase Reference)
• NIST Chemistry Reference: [((C₂H₅)3P)2Pd(S₂CNH(CH₂C₆H₅))]⁽¹⁺⁾*Cl^(1-)=[((C₂H₅)3P)2Pd(S₂CNH(CH₂C₆H₅))]Cl(90738-00-4)
• EPA Substance Registry System: [((C₂H₅)3P)2Pd(S₂CNH(CH₂C₆H₅))]⁽¹⁺⁾*Cl^(1-)=[((C₂H₅)3P)2Pd(S₂CNH(CH₂C₆H₅))]Cl(90738-00-4)

Safety Data

• Hazardous Substances Data: 90738-00-4(Hazardous Substances Data)

Upstream product

• 28425-04-9 dichlorobis(triethylphosphine)palladium(II) 
• 100-46-9 benzylamine 
• 90737-93-2 ((C₂H₅)3P)2Pd(S₂CN(CH₂C₆H₅)) 
• 1950-26-1 benzylammonium N-benzyldithiocarbamate 

Relevant articles and documents

Reactions of Transition Metal Compounds with Primary Amines and Carbon Disulfide: Dithiocarbimato and Dithiocarbamato Complexes of Palladium, Platinum, Nickel, Cobalt and Gold. X-Ray Structure of (Et3P)2MS2CNCH2Ph (M = Pd, Pt)

A series of dithiocarbimato complexes (R3P)2M(S2CNR') (1,2) has been obtained by reaction of (R3P)2MCl2 (M = Pd, Pt) with primary amines and carbon disulfide.The dithiocarbimato complexes 1 and 2 can be reversibly protonated to give the dithiocarbamato compounds (R3P)2M(+)Cl(-).The X-ray structures of the dithiocarbimato complexes (Et3P)2M(S2CNCH2Ph) (M = Pd, Pt) have been determined and the spectroscopic data (IR, 1H-, 13C-, 31P-, 195Pt-NMR) of the complexes are reported.The dithiocarbamato complexes (Ph3P)2MCl (M = Co, Ni), Ph3PAuS2CN(H)CH2Ph, Cl2Pt2 are formed from the corresponding chloro compounds, primary amine and CS2. - Key words: Dithiocarbimato, Dithiocarbamato Complexes, Palladium(II), Platinum(II), X-Ray