908142-08-5Relevant academic research and scientific papers
π-allyl palladium complexes as efficient and powerful alternative for nucleophilic substitution on bicyclo[3.1.0]hexane sulfonates: Regio-, chemo- and stereoselectivity
Lecornué, Frédéric,Charnay-Pouget, Florence,Ollivier, Jean
, p. 1407 - 1409 (2006)
The preparation of cyclopropylidene bicyclo[3.1.0]hexane derivatives has been performed on both exo- and endo-bicyclo[3.1.0]hexane sulfonates, through nucleophilic substitution via π-allyl palladium complexes. While the endo- and exo-configurations do not
Iron-Catalyzed Cross-Coupling of 1-Alkynylcyclopropyl Tosylates and Related Substrates
Tindall, Daniel J.,Krause, Helga,Fürstner, Alois
supporting information, p. 2398 - 2403 (2016/08/16)
1-Alkynylcyclopropyl tosylates react with alkylmagnesium halides in the presence of catalytic ferric acetylacetonate [Fe(acac)3] under net propargylic substitution; allene formation, which is the prevalent reactivity mode of propargylic substra
