908291-77-0Relevant academic research and scientific papers
A stereoselective synthesis of 6,6,6-trifluoro-l-daunosamine and 6,6,6-trifluoro-l-acosamine
Hayman, Colin M.,Larsen, David S.,Simpson, Jim,Bailey, Karl B.,Gill, Gurmit Singh
, p. 2794 - 2800 (2006)
A short synthesis of 6,6,6-trifluoro-l-acosamine 15 and 6,6,6-trifluoro-l-daunosamine 19 has been accomplished. The pyranose ring system of these carbohydrate analogues was formed by a hetero-Diels-Alder reaction of vinylogous imide 11 and ethyl vinyl eth
