908866-18-2

Upstream product

• 100-39-0 benzyl bromide 
• 924656-64-4 (E)-3-[(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-(2-[1,3]dithian-2-yl-ethyl)-oxepan-3-yloxy]-acrylic acid methyl ester 
• 908866-09-1 ((2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-but-3-enyl-oxepan-3-yloxy)-tert-butyl-dimethyl-silane 
• 908866-43-3 (2R,3S,5aR,7S,8R,10aS)-2-Allyl-8-benzyloxy-7-benzyloxymethyl-decahydro-1,6-dioxa-heptalen-3-ol 
• 908866-11-5 (2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-(2-[1,3]dithian-2-yl-ethyl)-oxepan-3-ol 
• 908866-15-9 (2R,5aR,7S,8R,10aS)-2-Allyl-8-benzyloxy-7-benzyloxymethyl-octahydro-1,6-dioxa-heptalen-3-one 
• 908866-12-6 (E)-3-[(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-(3-oxo-propyl)-oxepan-3-yloxy]-acrylic acid methyl ester 
• 908866-13-7 (1S,3R,7S,10R,12S,13R)-13-Benzyloxy-12-benzyloxymethyl-2,6,11-trioxa-tricyclo[8.5.0.0^3,7]pentadecan-5-one 
• 908866-07-9 (2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-hydroxymethyl-oxepan-3-ol 
• 850656-74-5 ((2R,4aR,6S,7R,9aS)-7-Benzyloxy-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-6-yl)-methanol 
• 908866-17-1 (2R,3R,5aR,7S,8R,10aS)-2-Allyl-8-benzyloxy-7-benzyloxymethyl-3-methyl-decahydro-1,6-dioxa-heptalen-3-ol 
• 69739-34-0 t-butyldimethylsiyl triflate 

Downstream Products

• 908866-19-3 3-[(2S,4aS,5aR,8R,9R,10aS,12aR)-8-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-phenyl)-8-methyl-decahydro-1,3,5,10-tetraoxa-benzo[b]heptalen-9-yl]-propan-1-ol 
• 908865-86-1 [(2R,3R,5aR,8R,10aS)-2-(3-Benzyloxy-propyl)-8-(4-methoxy-benzyloxy)-3-methyl-7-methylene-decahydro-1,6-dioxa-heptalen-3-yloxy]-tert-butyl-dimethyl-silane 
• 908866-20-6 [(2S,3R,5aS,7R,8R,10aR)-7-(3-Benzyloxy-propyl)-8-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-8-methyl-decahydro-1,6-dioxa-heptalen-2-yl]-methanol 
• 924656-65-5 [(2R,3R,5aR,7R,8R,10aS)-2-(3-Benzyloxy-propyl)-7-iodomethyl-8-(4-methoxy-benzyloxy)-3-methyl-decahydro-1,6-dioxa-heptalen-3-yloxy]-tert-butyl-dimethyl-silane 
• 908866-46-6 C₅₈H₉₈O₉Si₃ 
• 908866-26-2 C₆₀H₉₂O₉SSi₂ 
• 924656-32-6 C₆₆H₉₆O₉Si₂ 
• 908866-21-7 6-[7-(3-benzyloxy-propyl)-8-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-8-methyl-decahydro-1,6-dioxa-heptalen-2-ylmethyl]-2-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,9a-dimethyl-octahydro-1,5-dioxa-benzocyclohepten-7-ol 
• 908866-22-8 6-[7-(3-benzyloxy-propyl)-8-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-8-methyl-decahydro-1,6-dioxa-heptalen-2-ylmethyl]-2-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,9a-dimethyl-hexahydro-1,5-dioxa-benzocyclohepten-7-one 
• 908866-28-4 C₆₅H₁₀₄O₉Si₃ 
• 908866-23-9 C₆₆H₉₆O₁₁Si₂ 
• 908866-29-5 C₆₄H₁₁₂O₉Si₄ 
• 908866-27-3 C₆₆H₁₀₆O₉SSi₃ 
• 908866-24-0 6-[7-(3-benzyloxy-propyl)-8-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-8-methyl-decahydro-1,6-dioxa-heptalen-2-ylmethyl]-2-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,9a-dimethyl-octahydro-1,5-dioxa-benzocycloheptene-7,8-diol 

Relevant academic research and scientific papers

Total synthesis of the proposed structure of brevenal

Total synthesis of the proposed structure of brevenal, a natural marine polycyclic ether product, has been accomplished. The synthesis features (i) convergent synthesis of the pentacyclic polyether skeleton using our developed Suzuki-Miyaura coupling stra

Total synthesis, structure revision, and absolute configuration of (-)-brevenal

Total synthesis of structure 1 originally proposed for brevenal, a nontoxic polycyclic ether natural product isolated from the Florida red tide dinoflagellate, Karenia brevis, was accomplished. The key features of the synthesis involved (i) convergent ass