90928-94-2

Upstream product

• 685-83-6 bis(diethylamino)chlorophosphine 
• 576-83-0 2,4,6-trimethylphenyl bromide 

Downstream Products

• 1449302-99-1 mesitylphosphonous acid-borane bis(N,N-diethylamide) 
• 1449303-30-3 (trans-2,4,6-trimethylcyclohexa-1,4-dien-3-yl)phosphonic acid bis(N,N-diethylamide) 
• 1449303-31-4 phosphonous acid-borane bis(N,N-diethylamide) 
• 1449303-06-3 mesitylphosphonic acid bis(N,N-diethylamide) 
• 90929-05-8 C₂₅⁽¹³⁾CH₃₂NP 
• 90929-06-9 C₂₁⁽¹³⁾CH₂₂ClP 
• 90929-10-5 diethylamino(diphenylmethyl)-2,4,6-trimethylphenylphosphine 
• 90929-02-5 C₂₂H₂₂ClOP 
• 90929-04-7 C₂₁⁽¹³⁾CH₂₁P 
• 67565-91-7 mesityldiphenylmethylenephoshine 
• 67565-90-6 PCl(mesityl)CHPh₂ 

Relevant academic research and scientific papers

The reactivity of arylphosphorus acid amides under Birch reduction conditions

Several classes of arylphosphorus acid amides have been tested in reactions with alkali metal solutions in liquid ammonia. The outcomes of such reactions depend on the structures of the starting materials. Generally, two processes-Birch reduction or cleavage of the P-aryl bond-can be operative. Diarylphosphinic amides tend to undergo double Birch reduction to afford bis(cyclohexadienyl)phosphinic amides. Copyright

SYNTHESIS AND STRUCTURE OF ARYL-SUBSTITUTED PHOSPHA-ALKENES

An improved synthesis of the two triarylsubstituted phospha-alkenes mesityl (diphenylmethylene)phosphine (1a) and 2,6-dimethylphenyl(diphenylmethylene)phosphine (1b) described.Of several variants, the preferred route starts with the aryl bromides 4 which