67565-91-7Relevant academic research and scientific papers
A Lewis acid-mediated synthesis of P-alkyl-substituted phosphaalkenes
Bates, Joshua I.,Patrick, Brian O.,Gates, Derek P.
experimental part, p. 1660 - 1666 (2011/01/05)
Treating an equimolar mixture of R1P(SiMe3) 2 (R1 = tBu, Ad, Mes, Me3Si; Ad = 1-adamantyl, Mes = 2,4,6-trimethylphenyl) and R2C(O)R3 (R2:R3 = su
The addition polymerization of a P=C bond: A route to new phosphine polymers
Tsang, Chi-Wing,Yam, Mandy,Gates, Derek P.
, p. 1480 - 1481 (2007/10/03)
Addition polymerization, the most general method of preparation for organic polymers, has successfully been extended to P=C bonds. The polymerization of a phosphaalkene has been initiated by thermolysis or with alkyllithium reagents. The unprecedented pol
PROPERTIES OF SUBSTITUTED TRIARYLPHOSPHAALKENES
Does, T. van der,Bickelhaupt, F.
, p. 515 - 518 (2007/10/02)
(31)P NMR spectra of mesityl(diarylmesitylene)phosphines are presented and discussed in terms of the electronic nature and the configurational stability of the phosphorus-carbon double bond.
SYNTHESIS AND STRUCTURE OF ARYL-SUBSTITUTED PHOSPHA-ALKENES
Knaap, Th.A. van der,Klebach, Th.C.,Visser, F.,Bickelhaupt, F.,Ros, P.,et al.
, p. 765 - 776 (2007/10/02)
An improved synthesis of the two triarylsubstituted phospha-alkenes mesityl (diphenylmethylene)phosphine (1a) and 2,6-dimethylphenyl(diphenylmethylene)phosphine (1b) described.Of several variants, the preferred route starts with the aryl bromides 4 which
