90963-69-2Relevant academic research and scientific papers
PYRANDERIVATE DURCH -CYCLOADDITION ZWISCHEN α,β-UNGESAETTIGTEN CARBONYLVERBINDUNGEN UND PHOSPHACUMULENYLIDEN
Bestmann, H.J.,Schmid, G.
, p. 1441 - 1444 (2007/10/02)
α,β-Unsaturated carbonyl compounds 1 and phosphacumulene ylides 2 undergo a -cycloaddition with formation of pyran-substituted phosphoranes 3.Benzoic acid catalyzed Hofmann degradation of 3 yields the deeply coloured pyran derivatives 5.
