90985-55-0Relevant articles and documents
Ni-Al Bimetallic Catalyzed Enantioselective Cycloaddition of Cyclopropyl Carboxamide with Alkyne
Liu, Qi-Sheng,Wang, De-Yin,Yang, Zhi-Jun,Luan, Yu-Xin,Yang, Jin-Fei,Li, Jiang-Fei,Pu, You-Ge,Ye, Mengchun
, p. 18150 - 18153 (2017)
A Ni-Al bimetallic catalyzed enantioselective cycloaddition reaction of cyclopropyl carboxamides with alkynes has been developed. A series of cyclopentenyl carboxamides were obtained in up to 99% yield and 94% ee. The bifunctional-ligand-enabled bimetallic catalysis proved to be an efficient strategy for the C-C bond cleavage of unreactive cyclopropanes.