91000-43-0

Basic information

• Product Name: 3,5-dimethyl-N-[(E)-phenylmethylidene]aniline
• CAS NO: 91000-43-0
• Molecular Formula: C₁₅H₁₅N
• Molecular Weight: 209.2863
• Mol File: 91000-43-0.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 359.2°C at 760 mmHg
• Flash Point: 163.3°C
• Density: 0.95g/cm³
• Vapor Pressure: 5.01E-05mmHg at 25°C
• Refractive Index: 1.542
• CAS DataBase Reference: 3,5-dimethyl-N-[(E)-phenylmethylidene]aniline(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-dimethyl-N-[(E)-phenylmethylidene]aniline(91000-43-0)
• EPA Substance Registry System: 3,5-dimethyl-N-[(E)-phenylmethylidene]aniline(91000-43-0)

Safety Data

• Hazardous Substances Data: 91000-43-0(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 108-69-0 3,5-dimethylaminoaniline 
• 100-46-9 benzylamine 
• 124043-95-4 N-benzyl-3,5-dimethylaniline 
• 100-51-6 benzyl alcohol 
• 99-12-7 5-nitro-m-xylene 

Downstream Products

• 1075-70-3 benzaldehyde N,N-dimethylhydrazone 
• 1453874-99-1 methyl 1-(3,5-dimethylphenyl)-4-(2-methoxy-2-oxoethyl)-5-phenyl-1H-pyrrole-3-carboxylate 
• 150004-24-3 N,N-dibenzyl-3,5-dimethylaniline 
• 124043-95-4 N-benzyl-3,5-dimethylaniline 
• 1448450-28-9 2-(3,5-dimethylphenyl)-3-phenylisoquinolin-1(2H)-one 
• 1438900-71-0 N⁴,N^4'-dibenzyl-2,2',6,6'-tetramethyl-[1,1'-biphenyl]-4,4'-diamine 

Relevant articles and documents

Reductive Amination Revisited: Reduction of Aldimines with Trichlorosilane Catalyzed by Dimethylformamide─Functional Group Tolerance, Scope, and Limitations

Aldimines, generated in situ from aliphatic, aromatic, and heteroaromatic aldehydes and aliphatic, aromatic, and heteroaromatic primary or secondary amines, can be reduced with trichlorosilane in the presence of dimethylformamide (DMF) as an organocatalys

Dehydrogenation and α-functionalization of secondary amines by visible-light-mediated catalysis

A visible-light-mediated process for dehydrogenation of amines has been described. The given protocol showed a broad substrate scope, mild reaction conditions and excellent results without the requirement of tedious purification. This process can be applied in one-pot functionalization of secondary amines with various nucleophiles through the cooperation of visible-light and Lewis acid catalysis, leading to the structurally varied essential components of biologically active molecules. In addition, Stern-Volmer studies and quenching experiments revealed the role of a catalyst and led to the proposed mechanism of this transformation.

Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazoles, and Disulfides

A transition metal-free protocol has been developed for the oxidative coupling of primary amines to imines and azobenzenes, thiols to disulfides, and 2-aminothiophenols to benzothiazoles, offering excellent yields. The advantageous features of the present environmentally benign methodology include the usage of biocompatible and green reaction conditions such as, solvent, room temperature reactions and transition metal-free approach. Moreover, it offers a broader substrate scope.