910057-90-8Relevant articles and documents
Total synthesis of jimenezin via an intramolecular allylboration
Bandur, Nina G.,Brueckner, David,Hoffmann, Reinhard W.,Koert, Ulrich
, p. 3829 - 3831 (2007/10/03)
An efficient total synthesis of the annonaceous acetogenin jimenezin was achieved. The key steps used were a highly stereoselective intramolecular allylboration to establish the tetrahydropyran ring and an intramolecular Williamson reaction to close the tetrahydrofuran ring.