910058-01-4

Upstream product

• 910058-00-3 (S)-3-Benzyloxy-3-[(2S,5R,6S)-5-(tert-butyl-dimethyl-silanyloxy)-6-((Z)-dec-3-enyl)-tetrahydro-pyran-2-yl]-propan-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 163181-96-2 (S)-3-(benzyloxy)dihydrofuran-2(3H)-one 
• 910057-97-5 (4S,5S)-5-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-1,1-dimethoxy-heptan-4-ol 
• 910057-96-4 (3S,4S)-3-Benzyloxy-7,7-dimethoxy-heptane-1,4-diol 
• 910057-84-0 (S)-3-Benzyloxy-tetrahydro-furan-2-ol 
• 910057-88-4 (2S,3R,6S)-6-[(S)-1-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-(tert-butyl-dimethyl-silanyloxy)-2-((Z)-dec-3-enyl)-tetrahydro-pyran 
• 910057-86-2 2-{(E)-3-[(1S,2S)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-1-(3,3-dimethoxy-propyl)-butoxy]-allyl}-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 
• 910057-98-6 2-{(E)-2-[(1S,2S)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-1-(3,3-dimethoxy-propyl)-butoxy]-vinyl}-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 
• 910057-99-7 (2S,3R,6S)-6-[(S)-1-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-(tert-butyl-dimethyl-silanyloxy)-2-vinyl-tetrahydro-pyran 
• 910057-85-1 [(3S,4S)-3-benzyloxy-4-ethynyloxy-7,7-dimethoxy-heptyloxy]-tert-butyldimethylsilane 
• 910057-87-3 (2S,3R,6S)-6-[(S)-1'-benzyloxy-3'-hydroxy-propyl]-2-vinyl-tetrahydropyran-3-ol 

Downstream Products

• 910058-05-8 Toluene-4-sulfonic acid (1S,2R)-10-benzyloxy-1-{(S)-3-benzyloxy-3-[(2S,5R,6S)-5-(tert-butyl-dimethyl-silanyloxy)-6-((Z)-dec-3-enyl)-tetrahydro-pyran-2-yl]-propyl}-2-(tert-butyl-dimethyl-silanyloxy)-decyl ester 
• 910057-94-2 (2S,3R,6S)-3-tert-butyldimethylsilyloxy-6-{(2'S,5'R)-5'-[(1''S)-1''-tert-butyldimethylsilyloxy-9''-(1'''-phenyl-1H-tetrazolylsulfonyl)-nonyl]-tetrahydrofuran-2'-yl}-2-decyl-tetrahydropyrane 
• 910057-92-0 (2S,3R,6S)-6-[(1'S,4'S,5'R)-1',13'-dibenzyloxy-4'-hydroxy-5'-tert-butyldimethylsilyloxy-tridecanyl]-2-(Z)-dec-3''-enyl-3-tert-butyldimethylsilyloxy-tetrahydropyrane 
• 910058-06-9 Toluene-4-sulfonic acid (1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-{(S)-3-[(2S,5R,6S)-5-(tert-butyl-dimethyl-silanyloxy)-6-decyl-tetrahydro-pyran-2-yl]-3-hydroxy-propyl}-10-hydroxy-decyl ester 
• 910058-07-0 5-((R)-9-(tert-Butyl-dimethyl-silanyloxy)-9-{(2R,5S)-5-[(2S,5R,6S)-5-(tert-butyl-dimethyl-silanyloxy)-6-decyl-tetrahydro-pyran-2-yl]-tetrahydro-furan-2-yl}-nonylsulfanyl)-1-phenyl-1H-tetrazole 
• 910057-89-5 (2S,3R,6S)-6-[(1'S)-1'-benzyloxy-3'-iodo-propyl]-2-(Z)-dec-3''-3-tert-butyldimethylsilyloxy-tetrahydropyrane 

Relevant academic research and scientific papers

Total synthesis of jimenezin via an intramolecular allylboration

An efficient total synthesis of the annonaceous acetogenin jimenezin was achieved. The key steps used were a highly stereoselective intramolecular allylboration to establish the tetrahydropyran ring and an intramolecular Williamson reaction to close the tetrahydrofuran ring.