910057-86-2

Upstream product

• 910057-98-6 2-{(E)-2-[(1S,2S)-2-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-1-(3,3-dimethoxy-propyl)-butoxy]-vinyl}-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 
• 593-71-5 Chloroiodomethane 
• 910057-84-0 (S)-3-Benzyloxy-tetrahydro-furan-2-ol 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 163181-96-2 (S)-3-(benzyloxy)dihydrofuran-2(3H)-one 
• 910057-85-1 [(3S,4S)-3-benzyloxy-4-ethynyloxy-7,7-dimethoxy-heptyloxy]-tert-butyldimethylsilane 
• 910057-97-5 (4S,5S)-5-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-1,1-dimethoxy-heptan-4-ol 
• 910057-96-4 (3S,4S)-3-Benzyloxy-7,7-dimethoxy-heptane-1,4-diol 

Downstream Products

• 910058-05-8 Toluene-4-sulfonic acid (1S,2R)-10-benzyloxy-1-{(S)-3-benzyloxy-3-[(2S,5R,6S)-5-(tert-butyl-dimethyl-silanyloxy)-6-((Z)-dec-3-enyl)-tetrahydro-pyran-2-yl]-propyl}-2-(tert-butyl-dimethyl-silanyloxy)-decyl ester 
• 910057-94-2 (2S,3R,6S)-3-tert-butyldimethylsilyloxy-6-{(2'S,5'R)-5'-[(1''S)-1''-tert-butyldimethylsilyloxy-9''-(1'''-phenyl-1H-tetrazolylsulfonyl)-nonyl]-tetrahydrofuran-2'-yl}-2-decyl-tetrahydropyrane 
• 910057-92-0 (2S,3R,6S)-6-[(1'S,4'S,5'R)-1',13'-dibenzyloxy-4'-hydroxy-5'-tert-butyldimethylsilyloxy-tridecanyl]-2-(Z)-dec-3''-enyl-3-tert-butyldimethylsilyloxy-tetrahydropyrane 
• 910058-06-9 Toluene-4-sulfonic acid (1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-{(S)-3-[(2S,5R,6S)-5-(tert-butyl-dimethyl-silanyloxy)-6-decyl-tetrahydro-pyran-2-yl]-3-hydroxy-propyl}-10-hydroxy-decyl ester 
• 910058-07-0 5-((R)-9-(tert-Butyl-dimethyl-silanyloxy)-9-{(2R,5S)-5-[(2S,5R,6S)-5-(tert-butyl-dimethyl-silanyloxy)-6-decyl-tetrahydro-pyran-2-yl]-tetrahydro-furan-2-yl}-nonylsulfanyl)-1-phenyl-1H-tetrazole 
• 910058-01-4 Toluene-4-sulfonic acid (S)-3-benzyloxy-3-[(2S,5R,6S)-5-(tert-butyl-dimethyl-silanyloxy)-6-((Z)-dec-3-enyl)-tetrahydro-pyran-2-yl]-propyl ester 
• 910057-88-4 (2S,3R,6S)-6-[(S)-1-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-(tert-butyl-dimethyl-silanyloxy)-2-((Z)-dec-3-enyl)-tetrahydro-pyran 
• 910057-89-5 (2S,3R,6S)-6-[(1'S)-1'-benzyloxy-3'-iodo-propyl]-2-(Z)-dec-3''-3-tert-butyldimethylsilyloxy-tetrahydropyrane 
• 910058-00-3 (S)-3-Benzyloxy-3-[(2S,5R,6S)-5-(tert-butyl-dimethyl-silanyloxy)-6-((Z)-dec-3-enyl)-tetrahydro-pyran-2-yl]-propan-1-ol 
• 910057-99-7 (2S,3R,6S)-6-[(S)-1-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-(tert-butyl-dimethyl-silanyloxy)-2-vinyl-tetrahydro-pyran 
• 910057-87-3 (2S,3R,6S)-6-[(S)-1'-benzyloxy-3'-hydroxy-propyl]-2-vinyl-tetrahydropyran-3-ol 

Relevant academic research and scientific papers

Total synthesis of jimenezin via an intramolecular allylboration

An efficient total synthesis of the annonaceous acetogenin jimenezin was achieved. The key steps used were a highly stereoselective intramolecular allylboration to establish the tetrahydropyran ring and an intramolecular Williamson reaction to close the tetrahydrofuran ring.