910215-32-6

Basic information

• Product Name: tert-butyl[(2R,3R)-3-(4-methoxybenzyloxy)-2-methylpent-4-enyloxy]dimethylsilane
• Synonyms: tert-butyl[(2R,3R)-3-(4-methoxybenzyloxy)-2-methylpent-4-enyloxy]dimethylsilane
• CAS NO: 910215-32-6
• Molecular Weight: 350.574
• Mol File: 910215-32-6.mol

Chemical Properties

• CAS DataBase Reference: tert-butyl[(2R,3R)-3-(4-methoxybenzyloxy)-2-methylpent-4-enyloxy]dimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl[(2R,3R)-3-(4-methoxybenzyloxy)-2-methylpent-4-enyloxy]dimethylsilane(910215-32-6)
• EPA Substance Registry System: tert-butyl[(2R,3R)-3-(4-methoxybenzyloxy)-2-methylpent-4-enyloxy]dimethylsilane(910215-32-6)

Safety Data

• Hazardous Substances Data: 910215-32-6(Hazardous Substances Data)

Upstream product

• 910215-31-5 (2R,3R)-3-(4-methoxybenzyloxy)-2-methylpent-4-en-1-ol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 910215-30-4 (4R,5R)-2-(4-methoxyphenyl)-5-methyl-4-vinyl-1,3-dioxane 

Downstream Products

• 910215-36-0 (4R,5S,6S)-6-methoxy-5-(4-methoxybenzyloxy)-2,4-dimethylocta-2,7-dienyl hepta-2,6-dienoate 
• 910215-37-1 (9S,10S,11R)-9-methoxy-10-(4-methoxybenzyloxy)-11,13-dimethyloxacyclotetradeca-3,7,12-trien-2-one 
• 910215-28-0 tert-butyl[(2R,3S,4S)-4-methoxy-3-(4-methoxybenzyloxy)-2-methylhex-5-enyloxy]dimethylsilane 
• 910215-35-9 ethyl (4R,5S,6S)-6-methoxy-5-(4-methoxybenzyloxy)-2,4-dimethylocta-2,7-dienoate 
• 910215-26-8 (4R,5S,6S)-6-methoxy-5-(4-methoxybenzyloxy)-2,4-dimethylocta-2,7-dien-1-ol 
• 910215-34-8 (2R,3S,4S)-4-methoxy-3-(4-methoxybenzyloxy)-2-methylhex-5-en-1-ol 
• 910215-27-9 (2S,3S,4S)-4-methoxy-3-(4-methoxybenzyloxy)-2-methylhex-5-enal 
• 910215-29-1 (2S,3R)-4-(tert-butyldimethylsiloxy)-2-(4-methoxybenzyloxy)-3-methylbutyraldehyde 

Relevant articles and documents

A convergent synthesis of the macrolide core of migrastatin

We describe an efficient synthesis of the 14-membered macrolide core 2 of migrastatin via key intermediate 3 employing a diastereoselective aldol condensation, Lewis acid mediated diastereoselective addition and an exclusive (Z)-olefination sequence. Yama

A stereoselective synthesis of the macrolide core of migrastatin

A concise and efficient synthesis of the macrolide core of migrastatin, an antimetastatic agent, is reported. In this synthetic protocol, the key intermediate (4R,5S,6S)-6-methoxy-5-(4-methoxybenzyloxy)-2,4-dimethylocta-2,7- dien-1-ol is obtained after di