910311-16-9Relevant academic research and scientific papers
Synthesis of 2-cyclohexenone derivatives via gold(I)-catalyzed hydrative cyclization of 1,6-diynes
Zhang, Chen,Cui, Dong-Mei,Yao, Li-Ying,Wang, Bi-Song,Hu, Yong-Zhou,Hayashi, Teruyuki
, p. 7811 - 7813 (2008)
(Chemical Equation Presented) The gold(I) complex (MeAuPPh3) was found to be a highly effective catalyst for the hydrative cyclization of 1,6-diynes to form the corresponding 3-methyl hex-2-enone derivatives with good to excellent yield. The proposed mechanism is described.
