Synthesis of 2-cyclohexenone derivatives via gold(I)-catalyzed hydrative cyclization of 1,6-diynes

DOI: 10.1021/jo800974x

Source and publish data:

Journal of Organic Chemistry p. 7811 - 7813 (2008)

Update date:2022-08-04

Topics:

Authors:

Zhang, Chen

Cui, Dong-Mei

Yao, Li-Ying

Wang, Bi-Song

Hu, Yong-Zhou

Hayashi, Teruyuki

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Article abstract of DOI:10.1021/jo800974x

(Chemical Equation Presented) The gold(I) complex (MeAuPPh₃) was found to be a highly effective catalyst for the hydrative cyclization of 1,6-diynes to form the corresponding 3-methyl hex-2-enone derivatives with good to excellent yield. The proposed mechanism is described.

Full text of DOI:10.1021/jo800974x

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