910311-19-2Relevant academic research and scientific papers
Synthesis of 3-methyl-2-cyclohexenones catalyzed by mercury(II) salts and their microwave assisted BiCl3 catalyzed aldol condensations
Zhang, Chen,Wang, Bi-Song,Chen, Shi-Feng,Zhang, Shao-Qiao,Cui, Dong-Mei
experimental part, p. 165 - 169 (2011/02/17)
HgSO4 catalyzed hydrative cyclization of 1,6-heptadiynes is present. This reaction proceeded smoothly under the mild condition for differently 4-sustituted 1,6-diynic substrates giving corresponding 3-methyl-2-cyclohexenones with high to excell
Synthesis of 2-cyclohexenone derivatives via gold(I)-catalyzed hydrative cyclization of 1,6-diynes
Zhang, Chen,Cui, Dong-Mei,Yao, Li-Ying,Wang, Bi-Song,Hu, Yong-Zhou,Hayashi, Teruyuki
, p. 7811 - 7813 (2008/12/22)
(Chemical Equation Presented) The gold(I) complex (MeAuPPh3) was found to be a highly effective catalyst for the hydrative cyclization of 1,6-diynes to form the corresponding 3-methyl hex-2-enone derivatives with good to excellent yield. The proposed mechanism is described.
