91061-00-6Relevant academic research and scientific papers
"PALLADIUM COMPLEXES-KF / ALUMINA" CATALYSED EXCHANGE OF ALLYLIC GROUPS OF ESTERS WITH PHENOL
Muzart, J.,Genet, J.-P.,Denis, A.
, p. C23 - C28 (1987)
In the presence of KF/alumina and catalytic amounts of palladium complexes, phenol reacts with allylic esters under mild conditions to give the corresponding allyl phenyl ethers.
Preparation of γ-heterosubstituted allylindium and diindium reagents and their reactions with carbonyl compounds
Hirashita, Tsunehisa,Kamei, Toshiya,Horie, Tomoaki,Yamamura, Hatsuo,Kawai, Masao,Araki, Shuki
, p. 172 - 177 (2007/10/03)
Various γ-heteroatom-substituted allylindium reagents were prepared, and their reactions with carbonyl compounds were examined. The reaction of 1,3-dibromopropene with metallic indium gave two types of organoindium species, γ-bromoallylindium and allylic
Method for purification of alcohols
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, (2008/06/13)
A method for the purification of alcohols from organic soluble impurities has been discovered comprising treating the crude alcohol with a cyclic anhydride followed by an aqueous base and extracting the corresponding half-ester into aqueous solution leaving the impurities in organic solution. This method is particularly useful for the separation of chiral, nonracemic alcohols from the corresponding antipodal ester (the mixture resulting from an enzymatic kinetic resolution) because the separation is non-chromatographic and the enantiomeric integrity of the products is maintained.
